Analysis of Variables in Thin Film Reflection

Taylor Wrobel

MSE 3803




What was Done in Lab 8


The Blue Morpho Butterfly


Wing Structure


Multi-Layer Reflection


Wing reflects light at each layer of chitin

Reflected light gives the wing color

                              




Characteristics of Wing Color

Purely Reflected Light


All color caused by reflection

When back-lit, wing is brown, and nearly transparent


Pearlescent

Viewing angle changed color

Colors ranged from dark blue, to near white.


Dependent on Refractive Index


Refractive index of the medium impacted color

In air (n = 1.001)                                  In IPA (n = 1.37)



Exploring Wing Characteristics Through Simulation

Free Snell



Free software written in Scheme

Simulates light passing through layers

Controllable Variables


Substrate Refractive Index

Medium Refractive Index

Incident Angle

Number of Substrate Layers

Depth of Substrate Layers

Wing Sim

Application written to simplify simulation



Simulation Results


AND


Effects of Variables

Effect of Incident Angle


Simulation parameters constant apart from angle

Angle changed between 0 (normal) and 90 degrees (tangent)

10 degree increments

Total of 10 simulations

Angle Results


Effect of Number of Layers


Simulation parameters constant apart from number of layers

Number of layers changed between 10 and 100

10 layer increments

Total of 10 simulations

Number of LAyers Results


Effect of Layer Depth


Simulation parameters constant apart from layer depth

Layer depth changed between 90nm and 140nm

10nm increments

Total of 6 simulations

Layer Depth Results


Effect of Index of Refraction


Simulation parameters constant apart from medium refractive index

Substrate refractive index kept as chitin, n=1.57

Index changed between n=1.0 and n=2.0

Increments of 0.1

Total of 11 simulations

Refractive Index Results


Implications


As the medium and substrate refractive indices near each other, the spectrum darkens

If the indices were the same, it would reflect no light

This would require a fluid of around the same refractive index of chitin, n=1.57

Very few fluids have refractive indices that high, but silicon oil (n=1.52) may work

An Idea for Thought


A solution of arsenic trisulfide and sulfur in methylene iodide has a very high refractive index (n=1.9 approx)

With this high of an index used as a medium:

Resultant reflected spectrum would have same rough intensity as the spectrum in air

However, intensity would be centered around 660nm, producing a vibrant red.

References


Park, J.O. and Srinivasarao, M. (2013). MSE 3803 Class Materials. Georgia Tech School of Material Science.

Mohan Srinivasarao, "Nano-Optics in the Biological World: Beetles, Butterflies, Birds, and  Moths", Chem. Rev., 99, 1935 (1999).

The FreeSnell Thin-Film Optical Simulator
(http://people.csail.mit.edu/jaffer/FreeSnell/)


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