Spectroscopy

  • IR
  • UV-Vis
  • Florescence
  • NMR

 

NMR

IR

UV-Vis

Florescence

UV-Vis

  • 400nm-700nm range
  • Energy range of molecular orbitals

Infrared

  • 700nm -1mm range
  • Molecular vibrational Energy

Florescence

  • < .01nm
  • analogous to absorbtion
  • energy of band gaps

NMR

  • Nuclear Magnetic Resonance
  • 10m - 100m
  • spin energy measurement

Experiment 3

length of a molecule

Molecules of Interest

Anthracene

Napthalene

Napthacene

Bohr Model

Conjugated π system

  • delocalized electrons
  • quantized energy levels

Particle in a Box

When Classical Becomes Quantum

Derivation

  • wavelength -> frequency
  • frequency -> energy
  • energy -> length

Procedure

  • measure background spectra
  • measure sample

Results

Experiment 6 

functional group determination

Fourier Transforms

- not just for course 6

Interferometer

Procedure

  • measure background spectra
  • measure sample

Results

refer to paper copies

Experiment 8

magnetic spin decay

Decay

  • Γ - total spin decay rate
  • γ_2^* - pure dephasing (homogeneous)
  • γ_1 - damping (homogeneous)
  • Δ - inhomogeneous dephasing

Physical Aspect of Decay

  • γ_2^* - lost through collisions with conserved energy
  • γ_1 - decay excited state to ground state
  • Δ - change in phase due to the environment

<magnetic field illustration>

<spin decay and waves diagram>

Glycerol

Experiment Procedure

  • Total Decay
  • Spin Echo
  • Inversion Recovery

5.351 Oral

By Nchinda Nchinda

5.351 Oral

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